翻訳と辞書 |
Phosphoryl nitride : ウィキペディア英語版 | Phosphoryl nitride
Phosphoryl nitride in chemistry is a reactive intermediate with the structure OPN.〔Himmel, H.-J. and Linti, G. (2012), ''OPN and SPN: Small Molecules with Great Potential.'' Angew. Chem. Int. Ed., 51: 5541–5542. 〕 It is a linear oxygen phosphorus nitrogen molecule with a formal double bond between P and O (phosphoryl) and a triple bond (nitride) between P and N. It can be obtained in argon matrix isolation at 16 K by laser photolysis of phosphoryl triazide, OP(N3)3.〔''Elusive O═P≡N, a Rare Example of Phosphorus σ2λ5-Coordination'' Xiaoqing Zeng, Helmut Beckers, and Helge Willner Journal of the American Chemical Society 2011 133 (51), 20696-20699 〕 OPN and its isomer ONP can interconvert by photoisomerization. ==References==
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Phosphoryl nitride」の詳細全文を読む
スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース |
Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.
|
|